Morphology Transition and Aggregation-Induced Emission of an Intramolecular Charge-Transfer Compound

Abstract

An intramolecular charge-transfer (ICT) compound, (TCBD)2OPV3, has been synthesized and fabricated into one-dimensional nanotubes by a reprecipitation method. The observation of SEM and TEM showed the nanotubes were formed from their zero-dimensional precursors of hollow nanospheres. Reconstruction was found to happen during the morphology transition progress. The morphology transition and reconstruction are proposed to be a "curvature strain releasing" process driven by donor-acceptor dipole-dipole interactions. An aggregation-induced emission (AIE) effect was observed for (TCBD)2OPV3. Both aggregates of vesicles and nanotubes were observed to be good red emitters with near-infrared end emission of 750-850 nm, which endows the material with potential applications in the fields of optical devices, biosensors, and biolabels.