The Menschutkin reaction of 1-arylethyl bromides with pyridine: Evidence for the duality of clean SN1 and SN2 mechanisms

Structure and Mechanism in Organic Chemistry

Colin Eaborn · Journal of Organometallic Chemistry · 1970 · 1.1K citations

Natural Sciences, Chemistry, Enzyme Mechanism +11

The Correlation of Solvolysis Rates and the Classification of Solvolysis Reactions into Mechanistic Categories

S. Winstein, Ernest Grunwald, Howard Jones · Journal of the American Chemical Society · 1951 · 387 citations

Natural Sciences, Chemistry, Analytical Chemistry +6

The SN2-SN1 spectrum. 2. Quantitative treatments of nucleophilic solvent assistance. A scale of solvent nucleophilicities

Frank L. Schadt, T. William Bentley, Paul von Ragué Schleyer · Journal of the American Chemical Society · 1976 · 344 citations

Natural Sciences, Chemistry, Analytical Chemistry +4

Resonance Effect in Hammett Relationship. IV. Linear Free Energy Relationship based on the Normal Substituent Constants

Yasuhide Yukawa, Yuho Tsuno, Masami Sawada · Bulletin of the Chemical Society of Japan · 1966 · 246 citations · Full text

Natural Sciences, Chemistry, Chemical Kinetics +12

The SN2-SN1 spectrum. 1. Role of nucleophilic solvent assistance and nucleophilically solvated ion pair intermediates in solvolyses of primary and secondary arenesulfonates

T. William Bentley, Paul von Ragué Schleyer · Journal of the American Chemical Society · 1976 · 150 citations

Natural Sciences, Chemistry, Inorganic Chemistry +6