Publication | Closed Access
Nature of the Magnetic Interaction in the (Cu2+, Ln3+) Pairs: An Empirical Approach Based on the Comparison Between Homologous (Cu2+, Ln3+) and (NiLS2+, Ln3+) Complexes
240
Citations
0
References
1998
Year
Magnetic PropertiesEngineeringLow-dimensional MagnetismMagnetic ResonanceChemistryMagnetic MaterialsMagnetic Exchange InteractionsInorganic CompoundMagnetismIsomorphous Cu2+–ln3+ ComplexesMagnetic InteractionQuantum MaterialsComparison Between HomologousEmpirical ApproachInorganic ChemistryPhysicsPhysical ChemistrySpintronicsMolecule-based MagnetNatural SciencesCoordination ComplexApplied PhysicsCondensed Matter PhysicsMolecular ComplexMagnetic PropertyMetal Chain Compound
The magnetic interaction in a series of isomorphous Cu2+–Ln3+ complexes (1) is antiferromagnetic for LnCe, Nd, Sm, Tm, Yb and ferromagnetic for Ln=Gd, Tb, Dy, Ho, Er, while no interaction is operative for Ln=La, Pr, Eu, Lu.