Influence of manganese substitution on the microstructure and magnetostrictive properties of Co1−xMnxFe2O4 (x = 0.0–0.4) ferrite

Abstract

Manganese substituted cobalt ferrite, Co1−xMnxFe2O4 (x = 0.0–0.4), was prepared by a ceramic method. The heat-treated powders were pressed at hydrostatic pressure of 167 MPa, and were annealed at 1350 °C for 24 h. These samples present a single-phase cubic spinel structure and the compositional mass ratios are close to the empirical formula. The lattice constant determined from XRD increases with the increase of Mn content, whereas SEM study reveals that Mn substitution changes the microstructure and cause pores within the grains, which reduces the bulk density of the samples. The magnetocrystalline anisotropy constant, coercive field, and magnetostriction were observed to decrease with increasing Mn substitution; however, the strain derivative (dλ/dH) reaches a maximum value for x = 0.3. The observed variation in strain derivative in the Mn substituted cobalt ferrite is correlated to the microstructure whereas the reduced anisotropy of the system plays only a minor role.