Rhodium-catalysed asymmetric ring opening reactions with carboxylate nucleophiles

Conservation of Absolute Configuration in the Acyclic Rhodium-Catalyzed Allylic Alkylation Reaction:  Evidence for an <i>Enyl</i> (σ + π) Organorhodium Intermediate

P. Andrew Evans, Jade D. Nelson · Journal of the American Chemical Society · 1998 · 277 citations

Natural Sciences, Biochemistry, Chemistry +10

First Enantioselective Alkylations of Monosubstituted Allylic Acetates Catalyzed by Chiral Iridium Complexes

Jörg. P. Janssen, Günter Helmchen · Tetrahedron Letters · 1997 · 274 citations

Natural Sciences, Chemistry, Catalysis +15

Highly Selective Allylic Alkylation with a Carbon Nucleophile at the More Substituted Allylic Terminus Catalyzed by an Iridium Complex: An Efficient Method for Constructing Quaternary Carbon Centers

Ryo Takeuchi, Mikihiro Kashio · Angewandte Chemie International Edition in English · 1997 · 261 citations

Natural Sciences, Chemistry, Catalysis +13

Asymmetric Molybdenum-Catalyzed Alkylations

Barry M. Trost, Iwao Hachiya · Journal of the American Chemical Society · 1998 · 259 citations

Natural Sciences, Chemistry, Catalysis +7

Neutral alkylations via palladium(0) catalysis

Barry M. Trost, Gary A. Molander · Journal of the American Chemical Society · 1981 · 233 citations

Natural Sciences, Chemistry, Catalysis +13