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Synthesis and properties of tetrathiafulvalene–metal bisdithiolene macromolecules
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1979
Year
Materials ScienceInorganic ChemistryTetrasodium Tetrathiafulvalene-tetrathiolateTransition Metal ChalcogenidesEngineeringTransition Metal SaltsTetrathiafulvalene–metal Bisdithiolene MacromoleculesPhysical ChemistryReactivity (Chemistry)Tetrathiafulvalene-metal Bisdithiolene OligomersChemistryFunctional MaterialsSynthetic ChemistryInorganic SynthesisInorganic Compound
Reaction of tetrasodium tetrathiafulvalene-tetrathiolate with transition metal salts leads to the formation of tetrathiafulvalene-metal bisdithiolene oligomers which in the case of the nickel derivative possesses unusually high conductivity (ca. 30 Ω–1 cm–1).