Some types of organic high polymers and permutoids provided with active groups: Their synthesis, optical properties, and reactivity

Abstract

Abstract The synthesis and the properties of permutoids with ionic active groups and the kinetics of the decomposition of diazoacetic ester and of nitrosomethylurea through the ionic active groups are dealt with. A discussion follows of the synthesis of high polymers and permutoids with active groups of the chlorophyll and hemin series obtained by the introduction of the corresponding active groups into high‐polymeric compounds, by copolymerization, and by inclusion of the prosthetic group in the polycondensation process. A report is added on the optical properties of the high‐molecular compounds provided with active groups and on remarkable differences between low‐molecular compounds in a dissolved state and as active groups linked to high polymers. The apparatuses developed for taking absorption and reflection spectra are described. Finally, the catalytic effect of the high polymers provided with active groups of the hemin series is examined.