Ion−Solvent Interactions in Acetonitrile Solutions of Lithium Iodide and Tetrabutylammonium Iodide

Abstract

The vibrational spectra of acetonitrile solutions containing lithium iodide and tetrabutylammonium iodide have been studied using ATR-FTIR spectroscopy. The focus of interest was the effect of the iodide anion on the important vibrational bands of acetonitrile. The main effect of the LiI electrolyte is to shift the C⋮N stretching frequency in the blue direction due to interaction of the Li+ cation with the electronegative C⋮N group. However, a small red shift of the C⋮N stretching mode due to the interaction of I- with the methyl group of acetonitrile is found in both electrolytes. On the other hand, the symmetic and asymmetric stretching modes of the methyl group are significantly red shifted in the presence of LiI. Ab initio quantum chemical calculations were carried out to determine the optimum location of the Li+ and I- ions in ion−solvent complexes containing a varying number of solvent molecules. These calculations correctly predict the direction of the observed shifts for all the principal bands of acetonitrile except the methyl stretching modes.