Hydrogenation of Carbon Dioxide is Promoted by a Task‐Specific Ionic Liquid

Zhaofu Zhang, Ye Xie, S. Hu, Jinliang Song, Buxing Han

Angewandte Chemie International Edition · 2007 · 291 citations · 34 references

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Abstract

A basic hydrogenation catalyst: The combination of a basic ionic liquid (IL) and a supported ruthenium complex catalyzes the hydrogenation of CO2 with satisfactory activity and selectivity (see scheme). The resulting formic acid is easily collected and the ionic liquid and catalyst can be reused directly after an easy separation step. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z704487_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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