Concepedia

Continuous, selective hydroformylation in supercritical carbon dioxide using an immobilised homogeneous catalyst

Nicola Meehan, Martyn Poliakoff, Albertus J. Sandee, Joost N. H. Reek, Paul C. J. Kamer, Piet W. N. M. van Leeuwen

Chemical Communications · 2000 · 125 citations · 7 references

DOI

Concepts

Abstract

A continuous process for the selective hydroformylation of higher olefins in supercritical carbon dioxide (scCO2) is presented; the catalyst shows high selectivity and activity over several hours and no decrease in performance was observed over several days.

References

7

Rhodium-Catalyzed Hydroformylation in Supercritical Carbon Dioxide

Daniel Koch, Walter Leitner · Journal of the American Chemical Society · 1998 · 267 citations

, , +10

Organometallic Homogeneous Catalysis—Quo vadis?

Wolfgang A. Herrmann, B. Cornils · Angewandte Chemie International Edition in English · 1997 · 204 citations

, , +7

A Robust, Environmentally Benign Catalyst for Highly Selective Hydroformylation

Albertus J. Sandee, Lars A. van der Veen, Joost N. H. Reek et al. · Angewandte Chemie International Edition · 1999 · 131 citations

, , +12

Effect of Ligand Modification on Rhodium-Catalyzed Homogeneous Hydroformylation in Supercritical Carbon Dioxide

Daniel R. Palo, Can Erkey · Organometallics · 1999 · 118 citations

, , +14

The Continuous Acid-Catalyzed Dehydration of Alcohols in Supercritical Fluids:  A New Approach to the Cleaner Synthesis of Acetals, Ketals, and Ethers with High Selectivity

William K. Gray, Fiona Smail, Martin G. Hitzler et al. · Journal of the American Chemical Society · 1999 · 97 citations

, , +16