Concepedia

Rhodium-catalyzed Addition of Organo[2-(hydroxymethyl)phenyl]dimethylsilanes to Arenesulfonylimines

Yoshiaki Nakao, Masahide Takeda, Jinshui Chen, Tamejiro Hiyama, Yoshitaka Ichikawa, Ryo Shintani, Tamio Hayashi

Chemistry Letters · 2008 · 39 citations · 25 references

DOI

Concepts

Abstract

Abstract The title reaction is found to proceed in the presence of a rhodium/diene catalyst. Variously substituted diarylmethylamines and allylamines having an N-arenesulfonyl protection are obtained in good yields, which are important building blocks in organic synthesis.

References

25

Ns strategies: a highly versatile synthetic method for amines

Toshiyuki Kan, Tohru Fukuyama · Chemical Communications · 2004 · 509 citations

, , +13

Recent developments in asymmetric catalytic addition to CN bonds

Gregory K. Friestad, Alex K. Mathies · Tetrahedron · 2006 · 464 citations

, , +6

<i>C</i><sub>2</sub>-Symmetric Bicyclo[2.2.2]octadienes as Chiral Ligands:  Their High Performance in Rhodium-Catalyzed Asymmetric Arylation of <i>N</i>-Tosylarylimines

Norihito Tokunaga, Yusuke Otomaru, Kazuhiro Okamoto et al. · Journal of the American Chemical Society · 2004 · 426 citations

, , +13

Addition of Metalloid Hydrides to Alkynes: Hydrometallation with Boron, Silicon, and Tin

Barry M. Trost, Zachary T. Ball · Synthesis · 2005 · 396 citations

, , +13

Design of <i>C</i><i><sub>2</sub></i>-Symmetric Tetrahydropentalenes as New Chiral Diene Ligands for Highly Enantioselective Rh-Catalyzed Arylation of <i>N</i>-Tosylarylimines with Arylboronic Acids

Zhiqian Wang, Chen‐Guo Feng, Ming‐Hua Xu et al. · Journal of the American Chemical Society · 2007 · 375 citations

, , +11