Concepedia

Rhodium-Catalyzed Transannulation of 1,2,3-Triazoles with Nitriles

Tony Horneff, Stepan Chuprakov, Natalia Chernyak, Vladimir Gevorgyan, Valery V. Fokin

Journal of the American Chemical Society · 2008 · 518 citations · 26 references

DOIFull text

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Concepts

Abstract

Stable and readily available 1-sulfonyl triazoles are converted to the corresponding imidazoles in good to excellent yields via a rhodium(II)-catalyzed reaction with nitriles. Rhodium iminocarbenoids are proposed intermediates.

References

26

A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal Alkynes

Vsevolod V. Rostovtsev, Luke G. Green, Valery V. Fokin et al. · Angewandte Chemie International Edition · 2002 · 11.5K citations

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Peptidotriazoles on Solid Phase:  [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides

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Cu<sup>I</sup>‐Catalyzed Alkyne–Azide “Click” Cycloadditions from a Mechanistic and Synthetic Perspective

Victoria D. Bock, Henk Hiemstra, Jan H. van Maarseveen · European Journal of Organic Chemistry · 2005 · 1.4K citations

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Ruthenium-Catalyzed Cycloaddition of Alkynes and Organic Azides

Li Zhang, Xinguo Chen, Peng Xue et al. · Journal of the American Chemical Society · 2005 · 1.1K citations

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Ruthenium-Catalyzed Azide−Alkyne Cycloaddition: Scope and Mechanism

Brant C. Boren, Sridhar Narayan, Lars K. Rasmussen et al. · Journal of the American Chemical Society · 2008 · 804 citations

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