Friction of Gels. 7. Observation of Static Friction between Like-Charged Gels

Abstract

An extensive static friction has been observed when two like-charged polyelectrolyte gels are slid over each other in water. The two like-charged gel surfaces could not slip with each other at the initial shearing until the shear stress acting on the interface exceeded a certain critical value. The critical yield shear stress (static friction) and strain did not show a distinct dependence on the shearing rate but decreased with increasing temperature. The value of the static friction also increased with the increase in the normal pressure and effect of pressure becomes more substantial at a higher temperature. Furthermore, the static friction decreased 3−4 times when the counterions of the polyelectrolyte gels were changed from Na+ to Cs+. The observation of the static friction indicates that our previously proposed repulsion−adsorption model, which predicts a hydrodynamic mechanism with no static friction for two like-charged hydrogels in pure water, requires modification. Possible origins of the static friction are discussed.