Concepedia

Copolymerization of Vinyl Acetate with Ethylene by Palladium/Alkylphosphine−Sulfonate Catalysts

Shingo Ito, Kagehiro Munakata, A. Nakamura, Kyoko Nozaki

Journal of the American Chemical Society · 2009 · 210 citations · 21 references

DOI

Concepts

Abstract

Coordination copolymerization of vinyl acetate (VAc) with ethylene, leading to linear copolymers that possess in-chain -CH(2)CH(OAc)- units, has been accomplished using novel palladium complexes bearing alkylphosphine-sulfonate ligands.

References

21

Palladium catalysed copolymerisation of ethene with alkylacrylates: polar comonomer built into the linear polymer chainElectronic supplementary information (ESI) available: NMR data for entries 1, 9, 10, 12 and size exclusion chromatographic data for entries 1, 3, 8, 12. See http://www.rsc.org/suppdata/cc/b1/b111252j/

E. Drent, Rudmer van Dijk, Roel van Ginkel et al. · Chemical Communications · 2002 · 438 citations

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Nickel catalysis for ethylene homo- and co-polymerization

U. Klabunde, Steven D. Itten · Journal of Molecular Catalysis · 1987 · 330 citations

, , +12

Insertion Polymerization of Acrylate

Damien Guironnet, Philipp Roesle, Thomas Rünzi et al. · Journal of the American Chemical Society · 2008 · 282 citations · Full text

, , +13

Formation of Linear Copolymers of Ethylene and Acrylonitrile Catalyzed by Phosphine Sulfonate Palladium Complexes

Takuya Kochi, Shusuke Noda, Kenji Yoshimura et al. · Journal of the American Chemical Society · 2007 · 268 citations

, , +17

Copolymerization of Ethylene and Alkyl Vinyl Ethers by a (Phosphine- sulfonate)PdMe Catalyst

Shuji Luo, Javier Vela, G.R. Lief et al. · Journal of the American Chemical Society · 2007 · 234 citations

, , +14