Isoprene in the marine boundary layer (southeast Asian Sea, eastern Indian Ocean, and Southern Ocean): Comparison with dimethyl sulfide and bromoform

Abstract

Sampling for atmospheric isoprene and some other volatile organic compounds was conducted during two cruises in the austral summer, covering the western Pacific, eastern Indian Ocean, Southeast Asian Sea, and Southern Ocean. High isoprene levels were observed in the marine air masses over the southern Indian Ocean (up to 280 parts per trillion by volume (pptv)) and over the Southern Ocean (up to 60 pptv), as well as high levels of dimethyl sulfide and bromoform, both of which are mainly emitted by marine biota. It is highly probable that the high phytoplankton activity in the Southern Ocean during the austral summer was responsible for the high oceanic isoprene levels. The findings suggest a possible significant influence of oceanic isoprene on marine atmospheric chemistry.