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A Polymer‐Bound Chiral Template for Enantioselective Photochemical Reactions
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2008
Year
Chemical EngineeringEngineeringWang ResinPhotochemistrySynthetic PhotochemistryOrganic ChemistryHappy CoupleChemistryPolymer‐bound Chiral TemplateMpeg 2000Supramolecular PhotochemistryAsymmetric CatalysisPhotochromismEnantioselective SynthesisPolymers
A happy couple: A chiral complexing agent was modified with an ω-hydroxyalkyl linker and immobilized on a Wang resin and on a methoxypolyethylene glycol (MPEG 2000). The immobilized templates 1 served in an enantioselective photochemical reaction with impressive selectivity (e.r. 92:8 to 96:4) and stability over several cycles. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z802479_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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