Concepedia

Crossed Condensation of Two Different Hydrosulfido-Bridged Dinuclear Complexes: Structures and Reactivities of TiRu(3)S(4) Cubane-Type Sulfido Clusters This work was supported by a Grant-in-Aid for Specially Promoted Research (09102004) from the Ministry of Education, Science, Sports, and Culture of Japan.

Shin-ichiro Kabashima, Shigeki Kuwata, Keiji Ueno, Motoo Shiro, Masanobu Hidai

PubMed · 2000 · 40 citations · 0 references

Concepts

Abstract

A cube-shaped cluster, TiRu3S4, is derived from the selective combination of hetero- and homodinuclear fragments TiRuS2 and Ru2S2, respectively (see scheme). The clusters exhibit a fluxional, temperature-dependant behavior, ascribed to the proximity of Ru centers. [Ru]=Cp*Ru, [Ti]=CpTi.