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A new series of radical-cation salts based on asymmetrical ethylenedithiodimethyl-tetrathiafulvalene (EDTDM-TTF). Properties and crystal structure of (EDTDM-TTF)2PF6
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1985
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Materials ScienceInorganic ChemistryChemical EngineeringCrystal StructureEngineeringStructure ElucidationOrganic ChemistryNew SeriesChemistryRadical-cation SaltsOrganometallic PolymerInorganic SynthesisElectrochemistryInorganic Compound
A new series of radical-cation salts with inorganic anions PF6–, Br–, ClO4–, HgCl3–, I– has been prepared by electrochemical oxidation of ethylenedithiodimethyltetrathiafulvalene (EDTDM-TTF); the electrical conductivity and crystal structure of one of them, (EDTDM-TTF)2PF6, are reported and the three-dimensional character of its arrangement is suggested.