Concepedia

Spontaneous rearrangement in Corey's reaction

Robert F. Klein, Lisa M. Bargas, V. Horák, Mirtha Navarro

Tetrahedron Letters · 1988 · 15 citations · 5 references

DOIFull text

Open access

Concepts

Abstract

A 1H-NMR study of the oxidative deamination of sec-alkyl primary amines with 3,5-di-tert-butyl-1,2-benzoquinone confirmed spontaneous rearrangement of the quinone-imines to the respective aromatic Schiff bases.

References

5

Ground states of molecules. 38. The MNDO method. Approximations and parameters

Michael J. S. Dewar, Walter Thiel · Journal of the American Chemical Society · 1977 · 5.1K citations

, , +5

Oxidation of primary amines to ketones

E. J. Corey, Kazuo Achiwa · Journal of the American Chemical Society · 1969 · 151 citations

, , +8

Mild and simple biomimetic conversion of amines to carbonyl compounds

Thomas F. Buckley, Henry Rapoport · Journal of the American Chemical Society · 1982 · 101 citations

, , +7

Oxidative deamination of amines to ketones via oxaziridines

Stephen E. Dinizo, David S. Watt · Journal of the American Chemical Society · 1975 · 32 citations

, , +7

A facile biomimetic method for oxidative deamination of primary amines to aldehydes via transposition of an imine functionality

James H. Babler, Benedict J. Invergo · The Journal of Organic Chemistry · 1981 · 24 citations

, , +8