Assessment of a chlorine dioxide proprietary product for water and wastewater disinfection

Abstract

Chlorine on its own is adequate for many, if not most, potable water pre-oxidation and disinfection systems at plants where the application is straightforward. Similarly, most wastewater plants can be disinfected by chlorine in one of its commercially available forms. However, when more intense pre-oxidation is required or significant iron or manganese is present in a potable supply, the use of alternative disinfectants is often preferable. Similarly, when secondary problems are present in wastewater effluent, such as high ammonia, a stronger oxidant may be preferable. Hitherto, the use of stronger oxidants has been limited to large works due to the complexity of the operational processes required. Recently, the use of ozone has spread to smaller works as new developments in equipment have become available. However, chlorine dioxide has not been used in small works until now. This paper provides details regarding a product which is simply dissolved in water in tablet or granular form and generates chlorine dioxide on solution in water. The solution is stable over weeks or even months and can be used for disinfection and or pre-oxidation purposes. The chemical was assessed in a series of tests. The performance of the chlorine dioxide product was compared against sodium hypochlorite, for different water types. The reduction in microbial counts was monitored in a secondary effluent sample and a high-ammonia secondary effluent sample. The oxidation ability in a high iron and manganese water was also assessed. A cost assessment was carried out and compared to the use of sodium hypochlorite. Other factors such as safety ease of use, and storage requirements are discussed.Keywords: chlorine, chlorine dioxide, oxidant, iron, manganese