Chemical Communications · 2013 · 83 citations · 22 references
Natural SciencesChemistryMaterials ScienceColloid ScienceMaterials ChemistryNanomaterialsColloid ChemistryCrystal ChemistryCrystal EngineeringInorganic NanoparticlesNanoparticle DesignAqueous Reaction MediaAqueous Solvent EffectsColloidal CrystalsEnvironmental StabilityEnvironmental Stability TestingMetal-organic Framework SynthesisMetal-organic FrameworksThermal Stability Analysis
Methods are described to synthesize shape-selectable, monodisperse, aqueous-stable metal-organic frameworks (MOFs) by the reaction of aluminium nitrate with benzene tricarboxylic acid in various aqueous solvent mixtures and acetic acid as the capping ligand. Environmental stability was confirmed by thermal analysis and immersion in aqueous acidic media.
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Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
Eric D. Bloch, Wendy L. Queen, Rajamani Krishna et al. · Science · 2012 · 1.9K citations · Full text