Cu-catalyzed stereoselective conjugate addition of arylboronic acids to alkynoates

Catalytic Cycle of Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids. Arylrhodium, Oxa-π-allylrhodium, and Hydroxorhodium Intermediates

Tamio Hayashi, Makoto Takahashi, Yoshiaki Takaya et al. · Journal of the American Chemical Society · 2002 · 583 citations

Asymmetric 1,4-Addition, Rhodium-binap Complex, Chemical Engineering +14

Rhodium-Catalyzed Hydroarylation of Alkynes with Arylboronic Acids:  1,4-Shift of Rhodium from 2-Aryl-1-alkenylrhodium to 2-Alkenylarylrhodium Intermediate

Tamio Hayashi, Kazuya Inoué, Nobukazu Taniguchi et al. · Journal of the American Chemical Society · 2001 · 345 citations

Arylboronic Acids, Chemical Engineering, 2-Alkenylarylrhodium Intermediate +11

Copper-catalyzed addition of diboron reagents to α,β-acetylenic esters: efficient synthesis of β-boryl-α,β-ethylenic esters

Ji-Eon Lee, Jisook Kwon, Jaesook Yun · Chemical Communications · 2008 · 204 citations

Stereospecific synthesis of trisubstituted and tetrasubstituted olefins. Conjugate addition of dialkylcopper-lithium reagents to .alpha.,.beta.-acetylenic esters

E. J. Corey, John A. Katzenellenbogen · Journal of the American Chemical Society · 1969 · 184 citations

Tetrasubstituted Olefins, Engineering, Donut Icon +13

The Palladium‐Catalyzed Addition of Organoboronic Acids to Alkynes

Chang Ho Oh, Hyung Hoon Jung, Kiseong Kim et al. · Angewandte Chemie International Edition · 2003 · 176 citations

Asymmetric Catalysis, Chemical Engineering, Cross-coupling Reaction +9