Organic Letters · 2004 · 146 citations · 32 references
Natural SciencesChemical EngineeringChemistryCatalysisOrganic ChemistryReaction EngineeringCatalytic Reaction EngineeringOrganic SynthesisReactive Oxygen SpeciesRedox CatalysisCatalytic IntermediatesHydrocarbon ConversionHydrocarbon OxidationMild Reaction ConditionsOxygen Transfer ReactionsOxygenation
[Reaction: see text] Purely organic and catalytic systems of anthraquinones and N-hydroxyphthalimide efficiently promote oxygenation of hydrocarbons with dioxygen under mild conditions, e.g., fluorene can be converted completely to fluorenone with 85% yield at 80 degrees C.
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Cyclohexane oxidation continues to be a challenge
Ulf Schuchardt, Dilson Cardoso, Ricardo Sercheli et al. · Applied Catalysis A General · 2001 · 676 citations · Full text