Variation in the electron count and ground state of [Mn<sub>12</sub>O<sub>12</sub>(O<sub>2</sub>CR)<sub>16</sub>(H<sub>2</sub>O)<sub>4</sub>](R = Me or Ph) by metal substitution and redox changes: preparation and properties of [Mn<sub>8</sub>Fe<sub>4</sub>O<sub>12</sub>(O<sub>2</sub>CMe)<sub>16</sub>(H<sub>2</sub>O)<sub>4</sub>]·4H<sub>2</sub>O·2MeCO<sub>2</sub>H and [NPr<sup>n</sup><sub>4</sub>][Mn<sub>12</sub>O<sub>12</sub>(O<sub>2</sub>CPh)<sub>16</sub>(H<sub>2</sub>O)<sub>4</sub>]·H<sub>2</sub>O - Concepedia

Concepedia

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Variation in the electron count and ground state of [Mn<sub>12</sub>O<sub>12</sub>(O<sub>2</sub>CR)<sub>16</sub>(H<sub>2</sub>O)<sub>4</sub>](R = Me or Ph) by metal substitution and redox changes: preparation and properties of [Mn<sub>8</sub>Fe<sub>4</sub>O<sub>12</sub>(O<sub>2</sub>CMe)<sub>16</sub>(H<sub>2</sub>O)<sub>4</sub>]·4H<sub>2</sub>O·2MeCO<sub>2</sub>H and [NPr<sup>n</sup><sub>4</sub>][Mn<sub>12</sub>O<sub>12</sub>(O<sub>2</sub>CPh)<sub>16</sub>(H<sub>2</sub>O)<sub>4</sub>]·H<sub>2</sub>O

44

Citations

11

References

1992

Year

Ann R. Schake, Hui‐Lien Tsai, Nadine De Vries, Robert J. Webb, Kirsten Folting, David N. Hendrickson, George Christou

Journal of the Chemical Society Chemical Communications

Abstract

As a means of varying the electron count of complexes [Mn12O12(O2CR)16(H2O)4](1; R = Me or Ph), the aggregates [Mn8Fe4O12(O2CMe)16(H2O)4]2 and [NPrn4][Mn12O12(O2CPh)16(H2O)4]3 have been prepared; magnetochemical measurements confirm that the unusual of properties 1 can be significantly altered by ‘conversion’ to 2 and 3.

References

	Year	Citations

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