Concepedia

Synthesis and Structure of [MeAlN(2,6‐<i>i</i>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)]<sub>3</sub>: An Aluminum‐Nitrogen Analogue of Borazine

Krista M. Waggoner, Håkon Hope, Philip P. Power

Angewandte Chemie International Edition in English · 1988 · 120 citations · 2 references

DOI

Concepts

Abstract

A predominantly plannar Al3N3C6 core characterizes the structure of 1, the first trimeric iminoalane. The bond length equalization suggests a delocalization of the π-electrons and thus an analogy to borazoles. 1 is formed in a two-step reaction from AlMe3 and 2,6-diisopropylaniline with cleavage of methane. Aryl = 2,6-iPr2C6H3.

References

2

Synthesis and X‐Ray Structure of (2,4,6‐Me<sub>3</sub>C<sub>6</sub>H<sub>2</sub>BPC<sub>6</sub>H<sub>11</sub>)<sub>3</sub>: A Boron‐Phosphorus Analogue of Borazine

H. V. Rasika Dias, Philip P. Power · Angewandte Chemie International Edition in English · 1987 · 68 citations

, , +11

The crystal structure of Al4N4(C6H5)8

T. R. R. McDonald, Walter S. McDonald · Acta Crystallographica Section B · 1972 · 45 citations

, , +12