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Synthesis and Structure of [MeAlN(2,6‐<i>i</i>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)]<sub>3</sub>: An Aluminum‐Nitrogen Analogue of Borazine

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Citations

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References

1988

Year

Abstract

A predominantly plannar Al3N3C6 core characterizes the structure of 1, the first trimeric iminoalane. The bond length equalization suggests a delocalization of the π-electrons and thus an analogy to borazoles. 1 is formed in a two-step reaction from AlMe3 and 2,6-diisopropylaniline with cleavage of methane. Aryl = 2,6-iPr2C6H3.

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