Publication | Closed Access
A Three-Dimensional Ferrimagnet with a High Magnetic Transition Temperature (TC) of 53 K Based on a Chiral Molecule
277
Citations
12
References
2001
Year
The transparent, double bridged-(R)-spiral three-dimensional polymeric complex K<sub>0.4</sub> [Cr(CN)<sub>6</sub> ][Mn(S)-pn](S)-pnH<sub>0.6</sub> ((S)-pn=(S)-1,2-diaminopropane) has been synthesized and characterized (see X-ray structure; Cr: brown, Mn: red, C: gray, N: blue, K: green). Magnetic measurements on the complex show that the Mn<sup>II</sup> and Cr<sup>III</sup> ions interact ferrimagnetically and magnetic transition occurs at 53 K (Curie temperature).
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