Publication | Closed Access
A Novel Hybrid of Bi-Based High-<i>T</i><sub>c</sub> Superconductor and Molecular Complex
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Citations
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References
2003
Year
Superconducting MaterialEngineeringBismuth-based SuperconductorsIntercalation MethodChemistryMolecular Complex Hgi2py2Chemical EngineeringNovel SuperconductorsSuperconductivityQuantum MaterialsHigh Tc SuperconductorsSuperconducting DevicesInorganic ChemistryHigh-tc SuperconductivityPhysicsNew ConceptCatalysisHigh-temperature SuperconductivityNatural SciencesCoordination ComplexCondensed Matter PhysicsApplied PhysicsMolecular ComplexNovel Hybrid
Molecular complex HgI2Py2 (Py=pyridine) was intercalated into the Bi-based high-Tc cuprate by intercalative complexation. The intercalation method adopted in this work is based on the new concept, where a neutral ligating agent is diffused into the preintercalated HgI2 layer leading to a charge transfer-type complex formation between the Bi2O2 double layers of Bi2Sr2CaCu2Oy.
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