Publication | Closed Access
Generation of N-Heterocyclic Carbenes by Metal-Mediated Coupling of Propargylamine and Isocyanides
69
Citations
6
References
2005
Year
Chemical EngineeringIsocyanide LigandsPropargylic AlcoholEngineeringHeterocyclicAlkene MetathesisCross-coupling ReactionMetal-mediated CouplingN-heterocyclic CarbenesOrganic ChemistryCycloaddition ReactionOrganometallic CatalysisCatalysisChemistryHeterocycle ChemistryPharmacologySynthetic Chemistry
A new method for the synthesis of heterocyclic carbenes of imidazol-2-ylidene and oxazol-2-ylidene types implying a cycloaddition reaction of propargylamine and propargylic alcohol, respectively, to coordinated isocyanide ligands has been developed.
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