Concepedia

Palladium-Assisted Regioselective Olefin Insertion into and β-Hydrogen Elimination of Hydrogen−Molybdenum and −Tungsten Bonds. Synthesis and Reactions of Heterodinuclear Hydrido Complexes of Palladium and Platinum with Molybdenum and Tungsten

Ayako Kuramoto, Kouhei Nakanishi, T. Kawabata, Nobuyuki Komine, Masafumi Hirano, Sanshiro Komiya

Organometallics · 2005 · 24 citations · 14 references

DOI

Concepts

Abstract

Smooth reversible olefin insertion of ethyl acrylate, acrylonitrile, ethylene, dimethyl fumarate, and dimethyl maleate into MHCp(CO)3 (M = Mo (1a), W (1b)) has been catalyzed by Pd(PPh3)4 (4) or Pd(ethyl acrylate)(dppe) (8) at room temperature.

References

14

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