Physical Review · 1954 · 62 citations · 9 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsMaterials PhysicsMetallic MaterialsCrystal Field TheoryElectrical ConductivityElectronic Band StructureExchange InteractionsMetalsResistivity InterpretationCharge Exchange EffectsConductionCrystal Field Effects In Solid-state MaterialsCrystal-field EffectsRare Earth MetallurgyStark SplittingValence Electrons
It is shown that the anomalies observed in the resistance of the lighter rare-earth metals can be explained in form and order of magnitude by a simple model of the interaction between the conduction electrons and the $f$ electrons which are tightly bound to each atom. The $f$ electrons interact with the crystal field set up by the surrounding atoms, so that there is a Stark splitting of their energy levels. The extra resistance arises because ion cores with $f$ electrons in different states present different cross sections to the conduction electrons, and also because the conduction electrons can knock ions from one state to another. All exchange effects are neglected.
9
The Theory of Electric and Magnetic Susceptibilities
Clarence Zener · Physical Review · 1951 · 235 citations
Natural Sciences, Chemistry, Physics +11