Publication | Closed Access
The effect of N-methylation on the chemical reactivity of binuclear Ni amine-thiophenolate complexes
53
Citations
8
References
2001
Year
Inorganic ChemistryChemical EngineeringEngineeringBiochemistryNatural SciencesCoordination ComplexChemical ReactivityMolecular ComplexOrganometallic CatalysisChemistryBridging Halide IonTertiary Amine DonorsNin3 Core StructureInorganic Compound
Macrocyclic amine thiophenolate ligands are shown to form face-sharing bioctahedral nickel complexes with a central N3Ni(μ-SR)2(μ-Cl)NiN3 core structure. The bridging halide ion can be readily replaced when all six nitrogen atoms are tertiary amine donors.
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