Arabian Journal of Chemistry · 2012 · 26 citations · 15 references
EngineeringChemical EngineeringMaterials ScienceElectrochemical EngineeringElectrochemistryMarine MaterialsCarbon-based Energy MaterialsElectrochemical CellsElectrochemical Energy StorageElectrode MaterialsSupercapacitor MaterialsSupercapacitorsActivated CarbonCarbon ElectrodesElectrochemical CapacitorsElectrochemical ReversibilitySpecific Surface AreaSupercapacitor Energy StorageSurface AreaVoltammetry
In this paper, the synthesis and characterization of activated carbon from marine Posidonia Oceanica were studied. The activated carbon was prepared by a simple process namely pyrolysis under inert atmosphere. The activated carbon can be used as electrodes for supercapacitor devices. X-ray diffraction result revealed a polycrystalline graphitic structure. While scanning electron microscope investigation showed a layered structure with micropores. The EDS analysis showed that the activated carbon contains the carbon element in high atomic percentage. Electrochemical impedance spectroscopy revealed a capacitive behavior (electrostatic phenomena). The specific capacity per unit area of the electrochemical double layer of activated carbon electrode in sulfuric acid electrolyte was 3.16 F cm−2. Cyclic voltammetry and galvanostatic chronopotentiometry demonstrated that the electrode has excellent electrochemical reversibility. It has been found that the surface capacitance was strongly related to the specific surface area and pore size.
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Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer
John Chmiola, Gleb Yushin, Yury Gogotsi et al. · Science · 2006 · 3.9K citations
Natural Sciences, Materials Engineering, Materials Science +17
Frequency, thermal and voltage supercapacitor characterization and modeling
F. Rafik, H. Gualous, R. Gallay et al. · Journal of Power Sources · 2006 · 421 citations