International Journal of Modern Physics B · 2005 · 21 citations · 30 references
Natural SciencesPhysicsComputational ThermodynamicsCondensed Matter PhysicsThermodynamicsAb Initio MethodsHydrogen AtomInteratomic PotentialsMagnetic Properties Of SolidsPhase TransitionsInternal EnergyLocal-field EffectsMorse PotentialSpecific Heat CapacitySpecific Internal EnergySpin PolarizationSpin Polarization EffectsThermodynamic Analysis
In this paper we use the so-called static fluctuation approximation (SFA) to calculate the thermodynamic properties of spin-polarized atomic hydrogen. This approximation is based on the replacement of the square of the local-field operator with its mean value. A closed set of nonlinear integral equations is derived for neutral many-bosonic systems. This set is solved numerically by an iteration method for two triplet-state potentials: a Morse- and Silvera-type potentials. It is found that the mean internal energy per unit volume, the pressure, the entropy per unit volume, and the specific heat per unit volume increase with temperature and decrease with spin polarization in the low-temperature region (<8 mK ); whereas the condensate fraction increases with an applied magnetic field. It is also found that these quantities are nearly independent of spin polarization for high temperatures (>0.1 K ), and that they are independent of the number density up to 10 -3 Å -3 in the low-temperature region.
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