Concepedia

Synthesis and Characterization of Radical Cation Salts Derived from Tetraselenafulvalene and Bis(Ethy1enedithio)tetraselenafulvalene

L. K. Montgomery, T. Burgin, Chad Husting, L. Itlley, John C. Huffman, K. Douglas Carlson, J.D. Dudek, G.A. Yaconi, U. Geiser, Jack M. Williams

Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals · 1992 · 20 citations · 14 references

DOI

Concepts

Abstract

Abstract New synthetic routes to bis(ethylenedithio)tetraselenafulvalene (BETS) were explored, starting from tetraselenafulvalene (TSF). Several radical cation salts of TSF and BETS were prepared by electrocrystallization. A new kappa phase salt of BETS, K-(BETS)2GaCl4, displayed an interesting resistance-temperature profile from 300-35K.

References

14

Superconductivity in a synthetic organic conductor (TMTSF)2PF 6

D. Jérôme, A. Mazaud, M. Ribault et al. · Journal de Physique Lettres · 1980 · 1.4K citations · Full text

, , +10

Superconductivity at 33 K in CsxRbyC60

Katsumi Tanigaki, Thomas W. Ebbesen, Susumu Saito et al. · Nature · 1991 · 938 citations

, , +10

A new ambient-pressure organic superconductor, .kappa.-(ET)2Cu[N(CN)2]Br, with the highest transition temperature yet observed (inductive onset Tc = 11.6 K, resistive onset = 12.5 K)

Aravinda M. Kini, U. Geiser, Hau H. Wang et al. · Inorganic Chemistry · 1990 · 629 citations

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A New Ambient Pressure Organic Superconductor Based on BEDT-TTF with TC Higher than 10 K (TC=10.4 K)

Hatsumi Urayama, Hideki Yamochi, Gunzi Saito et al. · Chemistry Letters · 1988 · 530 citations

, , +17

Organic Superconductors—New Benchmarks

Jack M. Williams, Arthur J. Schultz, U. Geiser et al. · Science · 1991 · 392 citations

, , +14