Concepedia

Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia

Chemical Communications · 2009 · 44 citations · 6 references

Concepts

Chemical EngineeringEngineeringOrganic ElectrochemistryZinc ElectrodesUndivided CellMolecular ElectrochemistryElectrosynthesisZn-mediated Electrochemical AllylationCatalysisChemistryHomoallylic AlcoholsElectrochemistry

Abstract

An efficient electrosynthesis of homoallylic alcohols from allylic bromides and aldehydes in aqueous ammonia is achieved in an undivided cell fitted with a pair of zinc electrodes.

References

6

Aqueous Barbier-Grignard type reaction: Scope, mechanism, and synthetic applications

Chao‐Jun Li · Tetrahedron · 1996 · 489 citations

Cross-coupling Reaction, Organic Chemistry, Chemistry +3

Asymmetric synthesis of goniothalamin, hexadecanolide, massoia lactone, and parasorbic acid via sequential allylboration–esterification ring-closing metathesis reactions

P. Veeraraghavan Ramachandran, M. Venkat Ram Reddy, Herbert C. Brown · Tetrahedron Letters · 2000 · 102 citations

Engineering, Alkene Metathesis, Asymmetric Synthesis +8

Electrodeposition of zinc–nickel alloys from ammonia-containing baths

Israel Rodríguez, G. Valentin, François Lapicque · Journal of Applied Electrochemistry · 1999 · 66 citations

A Recyclable Electrochemical Allylation in Water

Zhenggen Zha, Ailing Hui, Yuqing Zhou et al. · Organic Letters · 2005 · 63 citations

Environmental Electrochemistry, C-c Bond Formation, Chemical Engineering +15

Application of Tin and Nanometer Tin in Allylation of Carbonyl Compounds in Tap Water

Zhiyong Wang, Zhenggen Zha, Cunliu Zhou · Organic Letters · 2002 · 53 citations