Journal of The Electrochemical Society · 1989 · 121 citations · 0 references
EngineeringMaterials EngineeringMaterials ScienceElectronic MaterialsInorganic ChemistrySensorsEnvironmental SensingHumidity EffectsHumidity SensorsMoisture SorptionRelative HumiditySensor MaterialsDefect PhysicsDefect StatesHumidityHumidity SensingHumidity Sensing MaterialsHumidity Sensing MechanismsHumidity Sensor MaterialsVapor Pressure
The humidity‐sensitive characteristics of La3+‐doped and undoped specimens were investigated at 400°C as a function of water vapor pressures. The conductivities of the specimens increased about one order of magnitude over the entire water vapor pressure range by the partial substitution of La3+ ions for Sr2+ in , accompanied by an increase in the humidity sensitivity. The origin of the increased sensitivity is discussed based on both changes in the defect structure of the specimens and in the behavior of chemisorbed water on the specimens. Furthermore, a sensing mechanism of a semiconductive humidity sensor is presented.