Publication | Closed Access
Isolation and conformation of a fully unsaturated nitrogen analogue of 18-crown-6
20
Citations
0
References
1986
Year
Inorganic ChemistryEngineeringBiochemistryFree LigandNatural SciencesCoordination ComplexPotassium ComplexStructure ElucidationMolecular ComplexChemistryHexa-aza MacrocycleUnsaturated Nitrogen AnalogueCrystallographyInorganic SynthesisBiomolecular EngineeringInorganic Compound
Reaction of the potassium complex of a hexa-aza macrocycle with 18-crown-6 affords the free ligand, which undergoes a conformational change upon complexation, according to spectroscopic and crystallographic studies.