Asymmetric synthesis of trans-2,5-diphenylpyrrolidine: A C2-symmetric chiral amine

.alpha.-Methoxy-.alpha.-trifluoromethylphenylacetic acid, a versatile reagent for the determination of enantiomeric composition of alcohols and amines

James A. Dale, David L. Dull, Harry S. Mosher · The Journal of Organic Chemistry · 1969 · 2.5K citations

Natural Sciences, Chemistry, Analytical Chemistry +6

Highly enantioselective borane reduction of ketones catalyzed by chiral oxazaborolidines. Mechanism and synthetic implications

E. J. Corey, Raman K. Bakshi, Saizo Shibata · Journal of the American Chemical Society · 1987 · 1.4K citations

Natural Sciences, Chemistry, Biocatalysis +10

A stable and easily prepared catalyst for the enantioselective reduction of ketones. Applications to multistep syntheses

E. J. Corey, Raman K. Bakshi, Saizo Shibata et al. · Journal of the American Chemical Society · 1987 · 864 citations

Natural Sciences, Chemistry, Catalysis +15

An efficient and catalytically enantioselective route to (S)-(-)-phenyloxirane

E. J. Corey, Saizo Shibata, Raman K. Bakshi · The Journal of Organic Chemistry · 1988 · 394 citations

Natural Sciences, Chemistry, Biocatalysis +6

Acyclic stereochemical control in free-radical reactions

Ned A. Porter, Bernd Giese, Dennis P. Curran · Accounts of Chemical Research · 1991 · 372 citations

Natural Sciences, Chemistry, Catalysis +7