Dalton Transactions · 2013 · 14 citations · 26 references
Natural SciencesChemistryMaterials ScienceCrystal StructureInorganic ChemistryPolymer ChemistryCoordination ChemistryCoordination PolymersPolymer PhysicsPolymer StructurePolymerization ChemistryTransition Metal ComplexesManganese ChemistryManganese Cluster StructureManganese OxidesMetal-ligand Coordination PolymersOne-dimensional Coordination PolymersPolymer Crystal StructurePolynuclear ComplexesSupramolecular Coordination Complexes
The first water soluble and crystallographically determined polynuclear Mn(II) complex, with water molecules bridging every two Mn centers, is reported. This is an unusual feature in 1D oligomer Mn(II) compounds with a nuclearity higher than 2. The polymer structure is largely preserved in water.
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Reticular synthesis and the design of new materials
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