Chemistry Letters · 1996 · 76 citations · 12 references
Inclusion-complex FormationCyclodextrin ProductionMicroscopic EnvironmentOrganic ChemistryChemistryIonic GuestsCyclodextrin CavityBiophysicsPolarized CavityHost-guest Chemistry
Abstract The pKa values and the 1H NMR spectra of tetraarylporphyrins in the presence of cyclodextrins suggest that the microscopic environment of the positively polarized cavity of cyclodextrin promotes the inclusion of the anionic guest and prohibits the penetration of the cationic guest into the cyclodextrin cavity.
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