Chemical Communications · 2012 · 98 citations · 48 references
Open AtmosphereChemical EngineeringCross-coupling ReactionEngineeringAlkene MetathesisSubstituted Alkene DerivativesOrganic ChemistryOrganometallic CatalysisCatalysisHomogeneous CatalysisChemistryRuthenium-catalyzed Oxidative CouplingHeteroaromatic EstersCatalytic Synthesis
A ruthenium-catalyzed oxidative coupling of substituted aromatic and heteroaromatic esters with alkenes in the presence of catalytic amounts of AgSbF(6) and Cu(OAc)(2) to provide highly substituted alkene derivatives in good to excellent yields under an open atmosphere is described.
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Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins
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