Concepedia

HYDRODIMERIZATION OF ACRYLIC ESTERS BY HALOGENOTRIS(TRIPHENYLPHOSPHINE) COBALT COMPLEXES

Hiroyoshi Kanai, Mitsuo Okada

Chemistry Letters · 1975 · 11 citations · 7 references

DOI

Concepts

Abstract

Abstract Acrylic esters were selectively hydrodimerized to adipic esters by halogenotris(triphenylphosphine) cobalt complexes in alcohol. The yield of a hydrodimer based on cobalt exceeded 100% in the presence of zinc. The addition of halides of alkali metals increased the yield.

References

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Electrolytic Reductive Coupling. VIII.<sup>1</sup> Utilization and a New Preparation of α-Methyleneglutaronitrile

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C. E. Rehberg, Marion B. Dixon, C. H. Fisher · Journal of the American Chemical Society · 1946 · 31 citations

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