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Induction of Mesomorphic Properties in Poly(propylene imine) Dendrimers and their Model Compounds
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2004
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Synthetic MacromoleculeEngineeringDepolymerizationPropylene IminePolymer ScienceMesomorphic PropertiesLyotropic Phase BehaviourMacromolecular SystemOrganic ChemistryChemistryModel CompoundsBiophysicsPolymer Chemistry
The lyotropic phase behaviour of selected dendrimers with non-mesomorphic peripheral units, i.e. decyloxybenzoyl substituted poly(propylene imine) dendrimers as well as model compounds of their main parts, i.e. decyloxybenzoyl substituted alkylamines and also derivatives of 1,4,7-triazacyclononane, has been studied. For the first time, the induction/variation of mesomorphic properties in binary systems of these dendrimers or of related model compounds with suitable organic solvents has been established.