Ring‐Strained Carbodiphosphoranes

Hubert Schmidbaur, Thomas Costa, B. MILEWSKI‐MAHRLA, Ulrich Schubert

Angewandte Chemie International Edition in English · 1980 · 58 citations · 11 references

Concepts

Abstract

The first rings to contain the structural unit PCP have been obtained by reaction of Ph2PCH2PPH2 with Br(CH2)nBr (n = 2, 3, 4). The chemical properties and the bond lengths and angles in carbodiphosphorane with n = 2 are best described by the following formulation:

References

11