Concepedia

Nucleophilicities and carbon basicities of DBU and DBN

Mahiuddin Baidya, Herbert Mayr

Chemical Communications · 2008 · 189 citations · 38 references

DOI

Concepts

Abstract

The nucleophilicity and Lewis basicity of DBU and DBN toward C(sp(2)) centers have been measured: nucleophilicities increase in the series DMAP < DBU < DBN < DABCO while Lewis basicities are DABCO < DMAP < DBU < DBN.

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