Publication | Closed Access
Formation of a Bowl‐Shaped, Pentacyclic Phosphonium Cage by Methylation of a Nucleophilic Phosphinidene
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Citations
29
References
2005
Year
EngineeringHeterocyclicNatural SciencesMolecular BiologyOrganic ChemistryPentacyclic Phosphonium CageChemistryReactive IntermediatePhosphinidene MoleculesNucleophilic Phosphinidene 1Heterocycle ChemistryNucleophilic PhosphinideneBiomolecular Engineering
Domino-cyclization of two phosphinidene molecules: Methylation of the nucleophilic phosphinidene 1 with MeOTf (OTf=triflate) affords the unusual phosphonium cage 2, which implies the formation of the novel phosphenium ion 3 as a reactive intermediate.
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