Enantioselective syntheses of a 1α-hydroxyvitamin D ring A precursor from 3-(triphenylsilyl)glycidol and from malic acid

The first practical method for asymmetric epoxidation

Tsutomu Katsuki, K. Barry Sharpless · Journal of the American Chemical Society · 1980 · 2.6K citations

Asymmetric Epoxidation, Altmetrics, Engineering +12

Catalytic asymmetric epoxidation and kinetic resolution: modified procedures including in situ derivatization

Yun Gao, Janice M. Klunder, Robert M. Hanson et al. · Journal of the American Chemical Society · 1987 · 1.9K citations

Chemical Engineering, Chemical Measurement, Engineering +13

Directed reduction of .beta.-hydroxy ketones employing tetramethylammonium triacetoxyborohydride

David A. Evans, Kevin T. Chapman, Erick M. Carreira · Journal of the American Chemical Society · 1988 · 941 citations

Novel Organocatalysts, Molecular Sciences, Engineering +12

Stereochemistry of alternating polyol chains: 13C NMR analysis of 1,3-diol acetonides

Scott D. Rychnovsky, Donald J. Skalitzky · Tetrahedron Letters · 1990 · 477 citations

Engineering, Organic Chemistry, 1,3-Diol Acetonides +8

Titanium(IV) Isopropoxide-Catalyzed Formation of 1-Substituted Cyclopropanols in the Reaction of Ethylmagnesium Bromide with Methyl Alkanecarboxylates

Oleg G. Kulinkovich, Sergei V. Sviridov, Dmitry A. Vasilevski · Synthesis · 1991 · 263 citations

Methyl Alkanecarboxylates, Chemical Engineering, 1-Substituted Cyclopropanols 2 +11