Energy & Fuels · 2008 · 17 citations · 15 references
EngineeringChemical EngineeringMaterials ScienceElectrochemical EngineeringElectrochemistryMembrane ScienceElectrochemical CellsFuel Cell MembranesFuel CellsMembrane CharacterizationMembrane EngineeringMembrane MaterialsFuel Cell DurabilityFuel Cell Membrane DurabilityGas Diffusion LayersMembrane DegradationMembrane PerformancePorosityProton Exchange Membrane Fuel CellsProton Exchange Membranes
This study exhibits a novel and simple process to test durability of the gas diffusion backing (GDB) with a microporous layer (MPL) and simulates operating a proton-exchange membrane fuel cell (PEMFC) that produces liquid water. One of the major concerns of the gas diffusion layer (GDL) inside a PEMFC is durability. From the analysis of morphology, resistance, and Gurley porosity, the characteristics of each GDL are compared. In long time water washing, the in-plane resistance of the GDL reduces from 29 to 23 mΩ/cm 2 over 200 h. The GDL shows a higher performance (1227 mA/cm 2 at 0.3 V) in long time water washing (200 h) than GDB at a low voltage region (1093 mA/cm 2 at 0.3 V). The high GDL degradation rate causes the migration of the site of MPL during water washing. The inside MPL is weaker than the outward on performance in a PEMFC, but it keeps performance better than GDB.
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PEM fuel cell electrocatalyst durability measurements
Rod L. Borup, John Davey, Fernando H. Garzón et al. · Journal of Power Sources · 2006 · 499 citations
Natural Sciences, Chemical Engineering, Materials Science +10
Micro-porous layer with composite carbon black for PEM fuel cells
Xiaolei Wang, Hongming Zhang, Jiezhen Zhang et al. · Electrochimica Acta · 2006 · 240 citations
Natural Sciences, Materials Engineering, Materials Science +14