Publication | Closed Access
The Effects of Binding Ligand Variation on the Nickel Catalyzed Externally Initiated Polymerization of 2‐Bromo‐3‐hexyl‐5‐iodothiophene
47
Citations
35
References
2009
Year
EngineeringOrganic ChemistryInitiated NiChemistryPolymersChemical EngineeringBinding Ligand VariationOrganometallic CatalysisHybrid MaterialsPolymer ChemistryMaterials ScienceInorganic ChemistryLigand VariationCatalysisPhosphine LigandsBiomolecular EngineeringPolymerization KineticsPolymer ReactionPolymer Synthesis
Abstract The effects of binding ligand variation on the externally initiated Ni catalyzed polymerization of P3HT were investigated using a novel methodology allowing facile screening of ligands. P3HT was synthesized with >80% initiator incorporation for both mono‐ and bidentate phosphine ligands. Variation of the initiating aryl group demonstrated vastly superior results for o ‐tolyl over p ‐tolyl substituents. magnified image
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