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Phosphorylated sugars. Part XVII. Synthesis of 3-deoxy-<scp>D</scp>-arabino-[1-<sup>14</sup>C]heptulosonic acid 7-(dihydrogen phosphate)
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1975
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Bioorganic ChemistryEngineeringGlycobiologyOrganic ChemistryPolysaccharideChemistryTitle CompoundEnzymatic ModificationBiosynthesisPart XviiSelective OxidationVanadium OxideBiochemistryBiocatalysisBiomolecular EngineeringHeterocyclicNatural SciencesDerivative (Chemistry)Synthetic Chemistry
The title compound was synthesised by addition of potassium [14C]cyanide to 2-deoxy-D-arabino-hexose 6-phosphate and selective oxidation of the resulting 3-deoxyheptonic acid 7-phosphate with chlorate and vanadium oxide.